Not an expert here but I think all cement products are extremely basic before they are activated and set, it’s part of the reaction that makes it harden. I can’t imagine it would remain that caustic once it has set and the reaction stops.I was just looking at the safety data sheet and noticed it has a pH of over 11 so you may want to plug up your drain holes, let some water stand in it a while, and then check the pH. Assuming it has adequately leached over the winter you may have knocked down the pH to the point it won’t burn plant roots, but I would definitely check before using.