In biology, especially cell biology, we consider every form of "action and response" a communication. I mean, our muscles work with acetylcholine, but that itself is evoked by chlorine (negative) and potassium, sodium or calcium (positive) potential difference.
Those electrical impulses sound pretty advanced, until you realize that even plant nutrient uptake is essentially the same principle; movement across a membrane based on simple values like -1, +1, -2 and +2, very rarely more than that.
A highly complex protein, responding to a highly complex volatile compound is usually no more complex than lego; if it fits, it fits. Combined, they fit to something else that in turn will shut a process on or off. Naphthalene acetic acid for instance, is not present a whole lot in nature, but it fits most auxin-related proteins and therefore acts as an auxin in most plants. Even though it physically differs a whole lot (it has no nitrogen) from indole-3-butyric acid (different structure) or indole-3-acetic acid (similar structure but different atomic makeup).
Ethylene from bananas can evoke strong responses in cucumbers and other fruits. It involves a whole bunch of cascades with fancy names and it looks super complex when you see those things mapped out. However, if you dive into the chemistry.. It's like: Block A and block /\ seem to fit nicely together, and the /A\ complex fits nicely into the ^ and all three combined form a triangle with four arms at the bottom. Those can hold on to the upper arms of the X and this leaves one position open for another ^ on the bottom of the X. This whole complex can bind to a protein, and once that happens it jumpstarts another cascade.
But in essence, all communication is simple in my view.
If you take a deep dive in the calvin cycle, you might see that there's a bunch of things involved in sun hitting the leaves. The sun is not actively receiving any communication in return, but the plant is sending a number of things out! Oxygen, water, reflected light, refracted light, just to name a few. The sun isn't very receptive to those things, but in a sense, the plant is communicating that it's receiving sunlight; it is sending out signals. Although the message is simple and we don't read much into it.. If we put more light into it, it will put more compounds out. Isn't that much like a conversation? A one sided one, I talk to myself sometimes too.
With a colleague I'm working on a project to see if we can non-invasively identify some kinds of breast cancers that hide better than other cancers, by simply watching what kind of molecules they put out. Once we get a full identification of all the molecules the cancer puts out, the whole process of future identification will be as simple as a plant receiving sunlight: feed the patient X and check if you can find Y.
Pretty cool stuff! But I think it's worth overthinking what we consider complex and simple communication. I believe that it's either simple or complex, depending on how you look at it. However I think it's unfair, unrealistic even, to say that one thing is simple and another is not.