I use copper sulphate on my junipers sometimes.
But.. I believe tip blight is rare. Most of the times I saw dying tips it was caused by root issues caused by bad watering.
True blight will show fruiting bodies or dots on the center of the foliage scales. If those aren't there, it's probably something else.
I'm even suspecting tip blight to be a naturally present degrading fungus that only attacks tips that are already dead or in a dying stage because blight also happens to occur on the compost heap where healthy branches go after they've been cut off. I can't back that up with literature, only by observations.
It seems that every time someone mentions tip blight on junipers, there seems to be some history of repotting or root cutting or over/underwatering and it seems that when left untreated it almost never returns the next year. That makes me question the cause and effect situation and the disease as a whole.
But copper sulphate is safe to use and if you think it'll help, I have nothing against that. It doesn't seem to hurt the trees at all and when used apropriately, it also doesn't hurt anything else.