I'm not aware of boiling water being used to germinate those species. It is sometimes used to kill diseases though not usually to boiling temp.
Boiling water is probably the easiest and safest to use so try it first.
The raspberry and pyracantha are fruits. Many fruiting plants have adapted to being eaten by birds. Many germinate much better after acid treatment to mimic passing through a bird's gut. You could try feeding them to some chickens but failing that sulfuric acid can be used.
I'm reluctant to encourage newbies who may not understand safety to play with strong acid but here's a link to the first page that came up when I searched acid treatment for seeds
https://depts.washington.edu/propplnt/Treatments to Overcome Seed Dormancy.htm#:~:text=Seeds, in small batches, are,appear dull after this treatment.