Hormex is fine to use.
Salicylic acid is the molecule itself, aspirin changes to it by releasing the acetyl-group in the presence of water.
Hormex contains indole-3-butyric acid and that is a stronger rooting hormone than salicylic acid; salicylic acid helps plants in a lot of ways, one of which is wound healing and growing more cells, in rooting there are just a few tried and tested ones that are classified as auxins - salicylic acid is not considered one, yet.
Mosses can take up hormones and aspirin and might use it for their own benefit or biochemical pathways instead of releasing it to your plant. This is something to take into account. The timing of your air layer is also important, because you want to make use of the naturally increased levels of auxins and add some on top to get the strongest response.
I do have to point out though, that I've seen in a bunch of the thousands of experiments I've done with plant hormones, additives can sometimes work counter productive.
Think of it as giving a person six beers every evening after dinner for a year, and then trying to get them drunk on four beers on a sunday afternoon.. Their body has adjusted to these high levels and they don't respond to it anymore. Plants can have a similar way of responding to hormone levels and become unable to root from there on forward. I have some plants from areas that were treated with agent orange and they are just about the only plant I have never, ever, ever, been able to multiply. Not even in tightly controlled tissue culture settings, and not even with 300+ media compositions with various hormones.
My junipers for instance, respond better and faster without the use of rooting hormones. I believe I'm seeing the same thing in my maples.