It depends which of the two routes you plan to go.
Are you planning on free form sort of sculpting a pot?
Or are you looking to make a mold and pouring it in?
I have experience with the former, using chicken wire, mesh, cement dye, and fast setting cement. So I can definitely help you there. Here is the thread on one of them
Just want to share my latest project, a cement forest pot I made for some zelkova and trident seedlings I had.
Zelkova were grown from seed started in maybe 2016/2017, trained independently and then assembled last spring. Tridents came from plantcitybonsai in 2016, and I was told they were 5-7 years old at the time. The dwarf azaleas I got this spring as 2" cuttings.
The first picture is a quick sketch before I started the whole project, the following the cement build, and then the composition as she sits now.
Just wanted to share, more to follow...